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國立清華大學化學系 Department of Chemistry
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蔡易州

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稱職：
教授兼理學院副院長
學歷：
美國麻省理工學院博士 (2001)
國立師範大學碩士 (1994)
國立師範大學學士 (1991)
辦公室位置：
化學館R508
辦公室分機：
實驗室分機：
 (03)5715131 ext 33341
(03)5715131 ext 33356
電子信箱：

經歷：
2022 ~
2012 ~
2015 ~ 2018
2008 ~ 2012
2003 ~ 2008
2001 ~ 2003
理學院副院長
國立清華大學教授
國立清華大學化學系系主任
國立清華大學副教授
國立清華大學助理教授
博士後研究：美國加州理工學院

研究領域：
有機、無機合成、無機材料及高分子合成應用於有機催化反應

期刊論文：
  1. Tsai, Y.-C.*; Lin, Y.-M.; Yu, J.-S. K. Hwang, J.-K. “A Three-Coordinate and Quadruply-Bonded Mo−Mo Complex” J. Am. Chem. Soc. 2006, 128, 13980-13981.
  2. Tsai, Y.-C.*; Wang, P.-Y.; Chen, S.-A.; Chen, J.-M. “Inverted-Sandwich Dichromium(I) Complexes Supported by two b-Diketiminates: A Multi-Electron Reductant and Syntheses of Chromium Dioxo and Imido” J. Am. Chem. Soc. 2007, 129, 8066-8067.
  3. Tsai, Y.-C.*; Lu, D.-Y; Lin, Y.-M.; Yu, J.-S. K. Hwang, J.-K. “Structural Transformations in Dinuclear Zinc Complexes Involving Zn-Zn Bonds” Chem. Commun. 2007, 4125-4127.
  4. Tsai, Y.-C.*; Wang, P.-Y.; Lin, K.-M.; Chen, S.-A.; Chen, J.-M. “Synthesis and Reactions of b-Diketiminato Divanadium(I) Inverted-Sandwich Complexes” Chem. Commun. 2008, 205-207.
  5. Tsai, Y.-C.*; Hsu, C.-W.; Yu, J.-S. K.; Lee, G.-H.; Wang, Y.; Kuo, T.-S. “Remarkably Short Metal-Metal Bonds: A Lantern-Type of Quintuply-Bonded Dichromium(I) Complex” Angew. Chem. Int. Ed. 2008, 47, 7250-7253. Reported by Nature “Photo finish for shortest metal-metal bond” doi:10.1038/news.2008.1042, highlighted by Nature Chemistry “Metal-metal bonds: Shorter and shorter” doi:10.1038/nchem.54, and by Science “Gold for the shortest bond” in the section of Editor’s Choice 2008, 321,1134.
  6. Hsu, C.-W.; Yu, J.-S. K.; Lee, G.-H.; Wang, Y.; Tsai, Y.-C.* “Quintuply-Bonded Dichromium(I) Complexes Featuring Metal-Metal Bond Lengths of 1.74 Å” Angew. Chem. Int. Ed. 2008, 47, 9933-9936.
  7. Tsai, Y.-C.*; Chen, H.-Z.; Chang, C.-C.; Yu, J.-S. K. ; Lee, G.-H. ; Wang, Yu ; Kuo, T.-S. “Journey from Mo–Mo Quadruple Bonds to Quintuple Bonds” J. Am. Chem. Soc. 2009, 131, 12534-12535.
  8. Lin, K.-M.; Wang, P.-Y.; Shieh, Y.-J.; Chen, H.-Z.; Kuo, T.-S.; Tsai, Y.-C.* “Reductive N–N bond cleavage and coupling of organic azides mediated by chromium(I) and vanadium(I) b-diketiminate” New. J. Chem. 2010, 34, 1737-1745.
  9. Chang, K.-C.; Lu, C.-F.; Wang, P.-Y.; Lu, D.-Y.; Chen, H.-Z.; Kuo, T.-S.; Tsai, Y.-C.* “Ligand-controlled synthesis of vanadium(I) β-diketiminates and their catalysis in cyclotrimerization of alkynes” Dalton Trans. 2011, 40, 2324-2331.
  10. Lu, D.-Y.; Yu, J.-S. K.; Kuo, T.-S.; Lee, G.-H.; Wang, Y.; Tsai, Y.-C.* “Theory-Guided    Experiments on the Mechanistic Elucidation of the Reduction of Dinuclear Zinc, Manganese, and Cadmium” Angew. Chem., Int. Ed. 2011, 50, 7611-7615.
  11. Wu, L.-C.; Hsu, C.-W.; Chuang, Y.-C.; Lee, G.-H.; Tsai, Y.-C.; Wang, Y.* “Bond Characterization on a Cr-Cr Quintuple Bond: A Combined Experimental and Theoretical Study” J. Phys. Chem. A 2011, 115, 12602-12615.
  12. Tsai, Y.-C. “The Chemistry of Univalent Metal β-Diketiminates” Coord. Chem. Rev. 2012, 256, 722-758.
  13. Liu, S.-C.; Ke, W.-L.; Yu, J.-S. K.; Kuo, T.-S.; Tsai, Y.-C.* “An Electron-rich Mo–Mo Quintuple Bond Spanned by One Lithium Atom: A New Type of Quintuple Bonding” Angew. Chem., Int. Ed. 2012, 51, 6394-6397.
  14. Huang, Y.-L.; Lu, D.-Y.; Yu, H.-C.; Yu, J.-S. K.; Hsu, C.-W.; Kuo, T.-S.; Lee, G.-H.; Wang, Y.; Tsai, Y.-C.* “Stepwise Construction of the Cr-Cr Quintuple Bond and Destruction Thereof Induced by Axial Coordination” Angew. Chem., Int. Ed. 2012, 51, 7781-7785.
  15. Chen, H.-Z.; Liu, S.-C.; Yen, C.-H.; Yu, J.-S. K. Shieh, Y.-J.; Kuo, T.-S.; Tsai, Y.-C.* “Reactions of Metal–Metal Quintuple Bonds with Alkynes: [2+2+2] and [2+2] Cycloadditions” Angew. Chem. Int. Ed. 2012, 51, 10342-10346.
  16. Wu, P.-F.; Liu, S.-C.; Shieh, Y.-J.; Kuo, T.-S.; Lee, G.-H.; Wang, Yu.; Tsai, Y.-C.* “Divergent Reactivity of Nitric Oxide with Metal–Metal Quintuple Bonds” Chem. Commun. 2013, 49, 4391-4393.
  17. Chen, H.-G.; Hsueh, H.-W.; Kuo, T.-S.; Tsai, Y.-C. “Haloacylation of the Quintuple-Bonded Group VI Metal Amidinate Dimers and Disproportionation of Acyl Groups to Form Carbynes” Angew. Chem. Int. Ed. 2013, 52, 10256-10260.
  18. Harisomayajula, N. V. S.; Nair, A. K.; Tsai, Y.-C. “Discovering Complexes Containing a Metal-Metal Quintuple Bond: From Theory to Practice” Chem. Commun. 2014, 50, 3391-3412.
  19. Nair, A. K.; Harisomayajula, N. V. S.; Tsai, Y.-C. “Theory, Synthesis and Reactivity of Quintuple Bonded Complexes” Dalton Trans. 2014, 43, 5618-5638.
  20. Nair, A. K.; Harisomayajula, N. V. S.; Tsai, Y.-C. “The Length of the Metal-to-metal Quintuple Bonds and Reactivity Thereof” Inorg. Chim. Acta. 2015, 424, 51-62.
  21. Lu, D.-Y.; Chen, P. P.-Y.; Kuo, T.-S.; Tsai, Y.-C. “The Mo-Mo Quintuple Bond as a Ligand to Stabilize Transition Metal Complexes” Angew. Chem. Int. Ed. 2015, 54, 9106-9110.
  22. Chang, T.-K.; Li, H.; Chen, K.-T.; Tsai, Y.-C.; Chi, Y.; Hsiao, T.-Y.; Kai, J.-J. "Substituent Effect of Ru(II)-Based Sensitizers Bearing a Terpyridine Anchor and a Pyridyl Azolate Ancillary for Dye Sensitized Solar Cells" J. Mater. Chem. A 2015, 3, 18422-18431.
  23. Satyachand Harisomayajula, N. V.; Chen, H.-G.; Kuo, T.-S.; Tsai, Y.-C.* "Reductive Cleavage of Acyl Halides to Carboxylato Alkylidyne Complexes from Their Reactions with the Quintuply Bonded Dimolybdenum Amidinate" Organometallics 2016, 35, 1534-1546.
  24. Lu, D.-Y.; Kuo, T.-S.; Tsai, Y.-C.* “A New Family of Multiply Bonded Dimolybdenum Boraamidinates with the Formal Mo-Mo Bond Orders of 3, 4, 4.5 and 5” Angew. Chem. Int. Ed. 2016, 55, 11614-11618.
  25. Wey, Y.-T.;Yang, F.-S.; Yu, H.-C.; Kuo, T.-S.; Tsai, Y.-C.* “Synthesis and Characterization of an Eclipsed Digermylene as a Building Block to Construct a Cyclic Octagermylene” Angew. Chem. Int. Ed. 2017, 56, 15108-15112.
  26. Huang, Y.-S.; Huang, G.-T.; Liu, Y.-L.; Yu, J.-S. K.; Tsai, Y.-C.* “Reversible Cleavage/Formation of the Cr-Cr Quintuple Bond in the Highly Regioselective Alkyne Cyclotrimerization” Angew. Chem. Int. Ed. 2017, 56, 15427-15431.
  27. Satyachand Harisomayajula, N. V.; Wu, B.-H.; Lu, D.-Y.; Kuo, T.-S.; Chen, I-C.*, Tsai, Y.-C.* “Ligand-Unsupported Cuprophilicity in the Preparation of Dodecacopper(I) Complexes and Raman Studies” Angew. Chem. Int. Ed. 2018, 57, 9925-9929.
  28. Satyachand Harisomayajula, N. V.; Makovetskyi, S.; Tsai, Y.-C.* “Cuprophilic Interactions in and between Molecular Entities” Chem. Eur. J. 2019, 57, 8936-8954.
  29. Yen, C.-H.; Lin, Y.-D.; Hsueh, H.-W.; Shieh, Y.-J.; Wu, P.-F.; Kuo, T.-S.; Tsai, Y.-C.*  “Chromium to Chromium Quintuple Bonds in a Trigonal Lntern Configuration” J. Chin. Chem. Soc. 2019, 66, 1047-1062.
  30. Tsai, Y-C. Molybdenum. In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 567–745.
    https://dx.doi.org/10.1016/B978-0-08-102688-5.00040-4
  31. Yang, C.-W.; Mallick, S.; Tsai,Y.-C.* “Facile Synthesis of “WCl3(DME)” and Structural and Electronic Characterizations” J. Chin. Chem. Soc. 2022, 69, 1431-1437.
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